To balance the equation (NH4)2SO4 + NaOH = Na2SO4 + NH3 + H2O using the algebraic method step-by-step, you must have experience solving systems of linear equations. The most common methods are substitution/elimination and linear algebra, but any similar method will work.
Step 1: Label Each Compound With a Variable
Label each compound (reactant or product) in the equation with a variable vĩ đại represent the unknown coefficients.
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a (NH4)2SO4 + b NaOH = c Na2SO4 + d NH3 + f H2O
Step 2: Create a System of Equations
Create an equation for each element (N, H, S, O, Na) where each term represents the number of atoms of the element in each reactant or product.
N: 2a + 0b = 0c + 1d + 0f H: 8a + 1b = 0c + 3d + 2f S: 1a + 0b = 1c + 0d + 0f O: 4a + 1b = 4c + 0d + 1f Na: 0a + 1b = 2c + 0d + 0f
Step 3: Solve For All Variables
Use substitution, Gaussian elimination, or a calculator vĩ đại solve for each variable.
- 2a - 1d = 0
- 8a + 1b - 3d - 2f = 0
- 1a - 1c = 0
- 4a + 1b - 4c - 1f = 0
- 1b - 2c = 0
Use your graphing calculator's rref() function (or an online rref calculator) vĩ đại convert the following matrix into reduced row-echelon-form:
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[ 2 0 0 -1 0 0] [ 8 1 0 -3 -2 0] [ 1 0 -1 0 0 0] [ 4 1 -4 0 -1 0] [ 0 1 -2 0 0 0]
The resulting matrix can be used vĩ đại determine the coefficients. In the case of a single solution, the last column of the matrix will contain the coefficients.
Simplify the result vĩ đại get the lowest, whole integer values.
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- a = 1 ((NH4)2SO4)
- b = 2 (NaOH)
- c = 1 (Na2SO4)
- d = 2 (NH3)
- f = 2 (H2O)
Step 4: Substitute Coefficients and Verify Result
Count the number of atoms of each element on each side of the equation and verify that all elements and electrons (if there are charges/ions) are balanced.
(NH4)2SO4 + 2 NaOH = Na2SO4 + 2 NH3 + 2 H2O
N | 2 | 2 | ✔️ |
---|---|---|---|
H | 10 | 10 | ✔️ |
S | 1 | 1 | ✔️ |
O | 6 | 6 | ✔️ |
Na | 2 | 2 | ✔️ |
Since there is an equal number of each element in the reactants and products of (NH4)2SO4 + 2NaOH = Na2SO4 + 2NH3 + 2H2O, the equation is balanced.
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